Lithium‐Aluminate‐Catalyzed Hydrophosphination Applications

VA Pollard, A Young, R McLellan… - Angewandte Chemie …, 2019 - Wiley Online Library
Synthesized, isolated, and characterized by X‐ray crystallography and NMR spectroscopic
studies, lithium phosphidoaluminate iBu 3 AlPPh 2 Li(THF) 3 has been tested as a catalyst for …

Comparing neutral (monometallic) and anionic (bimetallic) aluminum complexes in hydroboration catalysis: influences of lithium cooperation and ligand set

…, MÁ Fuentes, AR Kennedy, R McLellan… - Angewandte Chemie …, 2018 - Wiley Online Library
Bimetallic lithium aluminates and neutral aluminum counterparts are compared as catalysts
in hydroboration reactions with aldehydes, ketones, imines and alkynes. Possessing Li–Al …

Equity turbulence, fixed income illiquidity, and portfolio reallocation: The case for synthetic rebalancing

RI McLellan, W Kinlaw, E Abouzaid - Trading, 2009 - guides.pm-research.com
Equity Market reversals, combined with historically illiquid fixed income markets have left
many global plans out of balance. Analysis of 13 previous periods of market turbulence …

[HTML][HTML] Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications

VA Pollard, SA Orr, R McLellan, AR Kennedy… - Chemical …, 2018 - pubs.rsc.org
… Orr , Ross McLellan , Alan R. Kennedy ORCID logo , Eva Hevia ORCID logo and Robert E.
Mulvey … McLellan, GJ McNeil, RE Mulvey and SD Robertson, Polyhedron, 2016, 103, 94–99 …

[HTML][HTML] Levetiracetam versus phenytoin for second-line treatment of paediatric convulsive status epilepticus (EcLiPSE): a multicentre, open-label, randomised trial

…, Y Iqbal, S Rounding, J Mulligan, C Bell, S McLellan… - The Lancet, 2019 - thelancet.com
Background Phenytoin is the recommended second-line intravenous anticonvulsant for
treatment of paediatric convulsive status epilepticus in the UK; however, some evidence …

Donor‐influenced Structure–Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido‐Monohydrido‐Dialkylaluminates

LE Lemmerz, R McLellan, NR Judge… - … A European Journal, 2018 - Wiley Online Library
A series of heteroleptic monoamido‐monohydrido‐dialkylaluminate complexes of general
formula [iBu 2 AlTMPHLi⋅donor] were synthesized and characterised in solution and in the …

1‐Alkali‐metal‐2‐alkyl‐1, 2‐dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications

R McLellan, AR Kennedy, RE Mulvey… - … A European Journal, 2017 - Wiley Online Library
Equipped with excellent hydrocarbon solubility, the lithium hydride surrogate 1‐lithium‐2‐tert‐butyl‐1,2‐dihydropyridine
(1tLi) functions as a precatalyst to convert Me 2 NH⋅BH 3 to […

LiTMP Trans‐Metal‐Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion Traps

R McLellan, M Uzelac, AR Kennedy… - Angewandte Chemie …, 2017 - Wiley Online Library
Fluoroaromatic scaffolds pose a challenge to lithiation due to low stability of lithiated intermediates.
Here we apply trans‐metal‐trapping (TMT) to a series of key fluorinated aromatics. In …

Alkali metal and stoichiometric effects in intermolecular hydroamination catalysed by lithium, sodium and potassium magnesiates

…, C McLaughlin, AR Kennedy, R McLellan… - Dalton …, 2019 - pubs.rsc.org
Main group bimetallic complexes, while being increasingly used in stoichiometric deprotonation
and metal–halogen exchange reactions, have not yet made a significant impact in …

Facile Interchange of 3d and 4f Ions in Single‐Molecule Magnets: Stepwise Assembly of [Mn4], [Mn3Ln] and [Mn2Ln2] Cages within Calix[4]arene Scaffolds

MA Palacios, R McLellan, CM Beavers… - … A European Journal, 2015 - Wiley Online Library
The central Mn II ions in a series of calix[4]arene‐stabilised butterflies can be sequentially
replaced with Ln III ions, maintaining the structural integrity of the molecule but transforming its …